Carbon K-edge x-ray emission spectroscopy of gas phase ethylenic molecules

High-resolution X-ray emission and X-ray absorption spectroscopy.

In this review, high-resolution X-ray emission and X-ray absorption spectroscopy will be discussed. The focus is on the 3d transition-metal systems. To understand high-resolution X-ray emission and resonant X-ray emission, it is first necessary to spend some time discussing the X-ray absorption process. Section II discusses 1s X-ray absorption, i.e., the K edges, and section III deals with 2p X...

Communication: Near edge x-ray absorption fine structure spectroscopy of aqueous adenosine triphosphate at the carbon and nitrogen K-edges.

Near edge x-ray absorption fine structure (NEXAFS) spectroscopy at the nitrogen and carbon K-edges was used to study the hydration of adenosine triphosphate in liquid microjets. The total electron yield spectra were recorded as a function of concentration, pH, and the presence of sodium, magnesium, and copper ions (Na(+)/Mg(2+)/Cu(2+)). Significant spectral changes were observed upon protonatio...

Soft X-ray emission spectroscopy at the L-edge of transition metals in metalloproteins

Soft X-ray emission spectroscopy of aqueous myoglobin upon Fe 2p core excitation was carried out using a liquid cell with a 150 nm-thick polyimide window in a high vacuum chamber below 1×10−7 Pa. Fe 2p soft X-ray emission from the heme center of a met-myoglobin powder was effectively detected compared to that of an Fe2O3 powder. Fe 2p soft X-ray emission spectra for a series of aqueous-myoglobi...

X-ray absorption spectroscopy by full-field X-ray microscopy of a thin graphite flake: Imaging and electronic structure via the carbon K-edge

We demonstrate that near-edge X-ray-absorption fine-structure spectra combined with full-field transmission X-ray microscopy can be used to study the electronic structure of graphite flakes consisting of a few graphene layers. The flake was produced by exfoliation using sodium cholate and then isolated by means of density-gradient ultracentrifugation. An image sequence around the carbon K-edge,...

Nondipole Resonant X-ray-Raman Spectroscopy: Polarized Inelastic Scattering at the K Edge of Cl2